Examples of investigations

Selected results

Presentation of selected results of collaboration between Laboratory and scientists of the University and other academic and university institutions of Ukraine (papers with IF 0.5–6.8 only):

Demchenko P. X-ray powder diffractometry for solving the tasks of physics and chemistry of solids // XIV Scientific Conference “Lviv Chemical Readings-2013” / Collected Abstracts, Lviv, May 26–29, 2013. – P. У42.

ІIІ School for young scientists “Diffraction methods: from ideal to real structures”

Materials of practical training “X-ray powder diffraction methods. Phase analysis”.
September 26-27, 2013, Lviv.

Crystal structure determination

Solution and refinement of the crystal structure, X-ray qualitative and quantitative phase analysis

• Mykolaychuk O.G., Moroz N.V., Demchenko P.Yu., Akselrud L.G., Gladyshevskii R.E. Phase Relations in the Ag₈SnS₆–Ag₂SnS₃–AgBr System and Crystal Structure of Ag₆SnS₄Br₂ // Inorganic Materials. – 2010. – Vol. 46, No. 6. – P. 590–597.
• Demchenko P.Yu., Gladyshevskii R.E., Volkov S.V., Yanko O.G., Kharkova L.B., Fokina Z.A., Fokin A.A. The first nonaselenium ring // Chemical Communications. – 2010. – Vol. 46, Is. 25. – P. 4520–4522.
• Romaka L., Romaka V.V., Demchenko P., Serkiz R. Peculiarity of component interaction in Er–Fe–Sn ternary system at 670 and 770 K // J. Alloys and Compounds. – 2010. – Vol. 507. – P. 67–71.
• Shalapska T., Stryganyuk G., Gektin A., Demchenko P., Voloshinovskii A., Dorenbos P. Crystal structure and luminescence properties of LiYP4O12:Ce³⁺ phosphor // J. Physics: Condensed Matter. – 2010. – Vol. 22, No. 48. – P. 485503.
• Moroz M.V., Demchenko P.Yu., Akselrud L.G., Mykolaychuk O.G., Gladyshevskii R.E. Phase relations along the Ag₈GeS₆–[(AgBr)₄×GeS₂] cross-section. Crystal structure and electric conductivity of Ag₆GeS₄Br₂ in bulk // Chem. Met. Alloys. – 2010. – Vol. 3. – P. 161–168.
• Volkov S.V., Gladyshevskii R.E., Demchenko P.Yu., Yanko O.G., Akselrud L.G., Kharkova L.B., Fokina Z.A. Synthesis and crystal structure of Os₄S₁₁SeCl₈ // Chem. Met. Alloys. – 2010. – Vol. 3. – P. 191–196.
• Volkov S.V., Demchenko P.Yu., Akselrud L.G., Gladyshevskii R.E., Pekhnyo V.I., Fokina Z.A., Yanko O.G., Kharkova L.B. Crystal structure of osmium selenobromide OsSe₂Br₁₂ // Russian Journal of Inorganic Chemistry. – 2011. – Vol. 56, No. 3. – P. 387–391.
• Romaka L., Stadnyk Yu., Romaka V.V., Demchenko P., Stadnyshyn M., Konyk M. Peculiarities of component interaction in {Gd, Er}–V–Sn ternary systems at 870 K and crystal structure of RV₆Sn₆ stannides // J. Alloys and Compounds. – 2011. – Vol. 509. – P. 8862–8869.
• Volkov S.V., Gladyshevskii R.E., Mironov Yu.V., Demchenko P.Yu., Yanko O.G., Smolentsev A.I., Fokina Z.A., Kharkova L.B., Baranets S.A. Osmium ThioselenochlorideOs₂S₆Se₂Cl₈: Synthesis, cluster isolation, and structure // Russian Journal of Coordination Chemistry. – 2012. – Vol. 38, No. 3. – P. 171–176.
• Shalapska T., Stryganyuk G., Gektin A., Kotlov A., Demchenko P., Voloshinovskii A. Luminescence properties of Ce³⁺-doped NaPrP₄O₁₂ polyphosphate // J. Physics: Condensed Matter. – 2013. – Vol. 25, No. 10. – P. 105403.
• Demchenko P., Gektin A., Krasnikov A., Pashuk I., Shalapska T., Stryganyuk G., Voloshinovskii A., Zazubovich S. Energy migration and Gd³⁺↔Ce³⁺ transfer in Ce³⁺-doped GdP₃O₉ metaphosphate // J. Phys. D: Appl. Phys. – 2013. – Vol. 46, N. 23. – P. 235103.
• Баранец С.А., Демченко П.Ю., Янко О.Г., Харькова Л.Б., Гладышевский Р.Е., Николенко А.С., Волков С.В. Синтез и строение селенобромида рутения Ru₂Se₆Br₁₂ // Укр. хим. журн. – 2013.– Т. 79, № 3.– С. 7–9.
• Senchuk O., Demchenko G., Demchenko P., Gladyshevskii R. YNi₄Si – new derivative of CaCu₅ structure type // Visnyk of the Lviv University. Series Chemistry. – 2013. – Is. 54. – P. 77-83.
• Konyk M., Romaka L., Demchenko P., Romaka V. V., Stadnyk Yu., Horyn A. The V–Cu–Sb ternary system at 773 K: crystal, band structure, and physical properties // J. Alloys and Compounds. – 2014. – Vol. 589. – P. 200–206.
• Volkov S. V., Subbotin V. V., Demchenko P. Yu., Gladyshevskii R. E., Yanko O. G., Kharkova L. B. On the preparation, structure and bonding of ReSCl₃ // Chem. Met. Alloys. – 2015. – Vol. 8, Is. 1/2. – P. 43–54.
• Demchenko P., Khyzhun O. Y., Fochuk P. M., Levkovets S. I., Myronchuk G. L., Parasyuk O. V. Single crystal growth, structure and propertiesof TlHgBr₃ // Optical Materials. – 2015. – Vol. 49. – P. 94–99.

Microstructural investigations

RDF, FSDP, crystallite size, lattice strain, preffered orientation of the phase grains, composite material, etc.

• Trachevsky V.V., Steblenko L.P., Demchenko P.Y., Koplak O.V., Kuryliuk A.M., Melnik A.K. Changes in the state of paramagnetic centers and lattice parameter of micro-structured Si under the influence of weak magnetic field // Semiconductor Physics, Quantum Electronics & Optoelectronics. – 2010. – Vol. 13, N 1. – P. 87-90.
• Aksimentyeva O.I., Demchenko P.Yu., Savchyn V.P., Balitskii O.A. Structure, electrical and luminescent properties of the polyaniline–GaSe hybrid nanocomposites // Molecular Crystals and Liquid Crystals. – 2011. – Vol. 536. –P. 65/[297]–71/[303].
• Shevchuk V.N., Usatenko Yu.N., Demchenko P.Yu., Antonyak O.T., Serkiz R.Ya. Obtaining and observation of micro- and nano-sizeV₂O₅ structures // Functional Materials. – 2011. – Vol. 18, No.3. – P. 309–314.
• Opainych I.E., Aksiment’eva O.I., D’yakonov V.P., Piechota S., Ulański J., Demchenko P.Yu., Ukrainets’ A.M. Structure and thermodeformation properties of polymer–magnetite hybrid composites // Materials Science. – 2012. – Vol. 48, Is. 1. – P. 95–100.
• Balitskii O.A., Demchenko P.Yu., Mijowska (Borowiak-Palen) E., Cendrowski K. Synthesis and characterization of luminescent aluminium selenide nanocrystals // Mater. Res. Bull. – 2013. – Vol. 48. – P. 916–919.
• Aksimentyeva O.I., Demchenko P.Yu., Savchyn V.P., Balitskii O.A. The chemical exfoliation phenomena in layered GaSe-polyaniline composite // Nanoscale Research Letters. – 2013. – Vol. 8:29. – P. 29-1–29-5.
• Kulyk B., Figà V., Kapustianyk V., Panasyuk M., Serkiz R., Demchenko P. Structural properties and temperature behaviour of optical absorption edge in polycrystalline ZnO:X (Cu,Ag) films // Acta Physica Polonica A. – 2013. – Vol. 123, No. 1. – P. 92–97.
• Rakitskaya T.L., Kiose T.A., Zryutina A.M., Gladyshevskii R.E., Truba A.S., Vasylechko V.O., Demchenko P.Yu., Gryschouk G.V., Volkova V.Ya. Solid-State Catalysts Based on Bentonites and Pd(II) Cu(II) Complexes for Low-Temperature Carbon Monoxide Oxidation // Solid State Phenomena. – 2013. – Vol. 200. – P. 299–304.
• Shpotyuk M., Shpotyuk O., Golovchak R., Demchenko P. FSDP-related correlations in γ-irradiated chalcogenide semiconductor glasses: The case of glassy arsenic trisulphide g-As₂S₃ revised // Journal of Physics and Chemistry of Solids. – 2013. – Vol. 74. – P. 1721–1725.
• Kasian O.I., Luk’yanenko T.V., Demchenko P., Gladyshevskii R.E., Amadelli R., Velichenko A.B. Electrochemical properties of thermally treated platinized Ebonex® with low content of Pt // Electrochimica Acta. – 2013. – Vol. 109. – P. 630–637.
• Shpotyuk O., Kozyukhin S., Shpotyuk Ya., Demchenko P., Mitsa V., Veres M. Coordination disordering in near-stoichiometric arsenic sulfide glass // J. Non-Crystalline Solids. – 2014. – Vol. 402. – P. 236–243.
• Aksimentyeva O. I., Savchyn V. P., Dyakonov V. P., Piechota S., Horbenko Yu. Yu., Opainych I. Ye., Demchenko P. Yu., Popov A., Szymczak H. Modification of polymer-magnetic nanoparticles by luminescent and conducting substances // Molecular Crystals and Liquid Crystals. – 2014. – Vol. 590, Is. 1. – P. 35–42.
• Shmychkova O., Luk’yanenko T., Piletska A., Velichenko A., Gladyshevskii R., Demchenko P., Amadelli R. Electrocrystallization of lead dioxide: Influence of early stages of nucleation on phase composition // Journal of Electroanalytical Chemistry. – 2015. – Vol. 746. – P. 57–61.